How to choose the right UV adhesive with yellowing resistance for your needs?What methods can enhance the yellowing resistance of UV adhesives?
Selecting the right UV adhesive resistant to yellowing requires comprehensive consideration of the following aspects:
• Choose based on application scenarios and requirements
◦ Optical Applications: Select UV-curable adhesives with high transparency, low refractive index, and minimal shrinkage. For instance, those with a refractive index between 1.46-1.52 that match lens materials. BlueKelu L-6206 non-yellowing UV polyurethane resin offers high transparency and yellowing resistance, making it suitable for optical component encapsulation.
◦ Electronics field: For encapsulating electronic components, choose UV adhesives with superior temperature resistance. Examples include UVR-EP200 benzene-free epoxy acrylate electronic-grade resin, which withstands temperatures up to 160°C and maintains a ΔE < 1.0 yellowing index after 800 hours of UV exposure, protecting electronic components from high temperatures and yellowing.
◦ Crafts and Jewelry: Select UV-curable adhesives with varying viscosities based on the craft's form. For instance, Kasute UV thin-consistency adhesive is suitable for flow-through applications and heat-shrink films, while thick-consistency adhesive is ideal for shaping and ultra-thick consistency for large decorative items. All offer high transparency and yellowing resistance.
• Consider the strength of yellowing resistance: Different brands and models of UV adhesives exhibit varying levels of yellowing resistance. For applications requiring long-term exposure to intense UV radiation or high temperatures, select products with superior yellowing resistance. For instance, UVR-UV700 quantum dot-modified UV-resistant resin maintains a ΔE < 0.8 yellowing index after 5000 hours of UVB irradiation, meeting the demands of long-term outdoor use.
• Focus on curing conditions and speed: UV adhesive curing conditions and speed are also critical. If production line curing equipment has lower power, select UV adhesives requiring lower light intensity and faster curing speeds. Ensure the UV lamp wavelength matches the absorption peak of the photoinitiator to guarantee curing effectiveness.
•Consider environmental and safety requirements: For applications with stringent environmental standards, such as food packaging or children's toys, select UV-curable adhesives compliant with relevant eco-standards. Examples include UVR-BIO500 bio-based low-VOC yellowing-resistant resin, featuring VOC content <4.0g/L and meeting RoHS, REACH, and FDA 21CFR 175.300 food contact regulations.
• Reference brand reputation and product reviews: Renowned brands like Weiliugu and Kasute typically offer greater assurance in quality and performance. Their products have undergone market validation and enjoy favorable reputations. Additionally, review user feedback and case studies to assess actual application outcomes.
Enhancing the yellowing resistance of UV adhesives hinges on three key dimensions: raw material selection, formulation optimization, and process control. Specific approaches are outlined below:
1. Optimizing Raw Material Selection: Minimizing Yellowing Triggers at the Source
• Resins and Monomers: Prioritize yellowing-resistant base materials such as aliphatic polyurethane acrylates, epoxy acrylates (avoid aromatic resins prone to yellowing due to benzene ring oxidation), paired with yellowing-resistant monomers (e.g., di(2,2-dimethylpropyl) acrylate, tricyclodecanedimethanol diacrylate) to reduce oxidation and UV degradation risks at the molecular level.
• Photoinitiators: Select low-yellowing, residue-free types such as 1-hydroxycyclohexylphenyl ketone (HCPK), 2-Hydroxy-2-methyl-1-phenyl-1-propanone (1173). Avoid photoinitiators prone to decomposition that generate colored byproducts (e.g., benzoic acid esters) to minimize post-curing oxidation and yellowing of residual components.
• Anti-yellowing additives: Incorporate highly effective and stable additives, including UV absorbers (e.g., benzotriazoles, triazines, which absorb UV rays to prevent resin degradation) and antioxidants (e.g., hindered phenols, phosphite esters, which inhibit free radical oxidation reactions). Combining both significantly enhances long-term yellowing resistance.
2. Optimizing Production and Curing Processes: Minimizing External Influences
• Controlling Production Impurities: Prevent introducing metal ions (e.g., iron, copper ions, which catalyze oxidation) during manufacturing. Store raw materials in sealed, light-protected containers to avoid premature degradation. Ensure thorough mixing during adhesive preparation to prevent localized overheating that causes early yellowing.
• Optimize curing parameters: Employ “low-intensity, extended duration” or staged curing methods to prevent localized overheating during curing (high temperatures accelerate resin oxidation and photoinitiator residue decomposition). Ensure UV lamp wavelength matches the photoinitiator's absorption peak (typically 365nm or 395nm) to guarantee complete curing and minimize unreacted components (uncured monomers/resins prone to post-curing oxidation and yellowing).
3. Enhance Post-Curing Protection: Mitigate Environmental Impacts
• Surface Coating Protection: For outdoor or high-UV applications, apply a UV-resistant topcoat (e.g., fluorocarbon or silicone coating) over the cured adhesive layer to further shield against UV radiation and oxygen, extending yellowing resistance.
• Control usage environment: Avoid prolonged exposure of bonded components to high temperatures (recommended maximum 80°C, subject to adhesive temperature rating), high humidity, or intense UV (e.g., direct outdoor sunlight). Where necessary, incorporate physical light-shielding/heat-insulating structures (e.g., lampshades, protective casings).





